Material is the everyday word — it can mean a substance something is made from, fabric, content for a book or show, or something significant to a case. Materiel is a narrower, specialist term used almost only in a military context, for equipment and supplies. If you're not talking about an army's kit, you almost certainly want material.
The core difference
Material is the broad, everyday word for substances, fabric or content, while materiel is a specialist term limited to military equipment and supplies.
- material — a substance something is made from, or fabric, or content, or something significant: Builders are struggling to source enough material for the new houses.
- materiel — military equipment, apparatus and supplies: The convoy was carrying materiel for the forward base.
How to tell them apart
The two words share a Latin root and, via French, a common ancestor — materiel is essentially the same word borrowed a second time with a narrower, military sense attached. That shared history explains why the spellings look so close, but the usage doesn't overlap: materiel almost never appears outside logistics, defence and military reporting, while material covers everything from curtain fabric to a comedian's new jokes.
A simple memory hook: materiel keeps the French flavour of its ending, much like matériel in the original — think of it as the word that stayed in uniform.