Unconscious has two very different jobs: it describes someone who has passed out, and it describes thoughts or actions done without conscious awareness. Subconscious only does the second job, describing the layer of mind working quietly beneath your awareness. A boxer knocked out is unconscious, never subconscious.
The core difference
Unconscious covers both a physical blackout and unaware mental activity, while subconscious refers only to the mind's below-awareness layer.
- unconscious — not awake and unaware of surroundings, or done without conscious intention: He was knocked unconscious during the match.
- subconscious — happening in the part of the mind we are not actively aware of: His subconscious fears showed up in his dreams.
How to tell them apart
Think of unconscious as the wider word: it stretches from a medical state, someone who has fainted or been knocked out, all the way to an unnoticed mental habit, like an unconscious bias. Subconscious stays narrower and only ever refers to that quiet, below-awareness layer of the mind, never to a physical blackout.
The mix-up usually happens in psychology or self-help writing, where people reach for subconscious as a catch-all for anything the mind does without us noticing. If the sentence could also describe someone lying still on the floor after a fall, unconscious is the safer choice.